Reversible carbon–boron bond formation at platinum centers through σ-BH complexes†
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DOI: 10.1039/d0sc05522k
Abstract: A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(ItBuiPr′)(ItBuiPr)][BArF], 1, with tricoordinated boranes HBR2. X-ray diffraction studies provided structural snapshots of the sequence of reactions… read more here.
Keywords: carbon; boron bond; carbon boron; formation ... See more keywords