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Published in 2020 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-020-02647-3
Abstract: Boron-based materials have been studied extensively due to their potential applications in hydrogen storage and sensing. Doping their surface with transition metals can improve their electronic properties and chemical reactivity. Here, we have studied the…
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Keywords:
titanium doped;
boron;
doped boron;
boron cluster ... See more keywords
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Published in 2019 at "Bioorganic chemistry"
DOI: 10.1016/j.bioorg.2019.103466
Abstract: In this study, a series of uridine (U) and 2'-deoxyuridine (dU) conjugates containing an isomeric ortho-, meta- or para-carborane cluster (C2B10H12) attached at C-5 through an ethynyl linker were synthesized. The effect of carborane cluster…
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Keywords:
uridine deoxyuridine;
carborane;
boron cluster;
para ... See more keywords
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Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00826e
Abstract: Bromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid. In contrast to the unsubstituted parent compound, 4-Br-anti-B18H21 possesses dual emission upon…
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Keywords:
oxygen;
cluster based;
boron cluster;
molecular boron ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc07075d
Abstract: This study presents the activity of a series of 1,8-naphthalimide-carborane/metallacarborane conjugates against Rhabditis sp. The carborane conjugates were the least active. Selected conjugates with cobaltacarborane (5 and 6) showed high activity. Their lethal concentration (LC50)…
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Keywords:
naphthalimide boron;
cluster conjugates;
activity naphthalimide;
boron cluster ... See more keywords
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Published in 2020 at "Russian Journal of Inorganic Chemistry"
DOI: 10.1134/s0036023620040026
Abstract: Abstract Data on the known-to-date copper(II) complexes with neutral nitrogen-containing ligands (2,2'-bipyridyl, 1,10-phenanthroline, 2,2'-bipyridylamine, aminoguanidine, ammonia, pyridine derivatives, etc.) with boron cluster anions, including those containing bridging OH – and $${\text{CO}}_{3}^{{2 - }}$$ groups, are…
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Keywords:
copper;
copper complexes;
complexes neutral;
cluster anions ... See more keywords
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Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms24010306
Abstract: Among the great variety of anti-cancer therapeutic strategies, boron neutron capture therapy (BNCT) represents a unique approach that doubles the targeting accuracy due to the precise positioning of a neutron beam and the addressed delivery…
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Keywords:
effect;
boron delivery;
boron cluster;
boron ... See more keywords