A highly fluorescent tri-nuclear boron complex with large Stokes shifts based on tripodal Schiff base: synthesis and photophysical properties
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-019-1643-4
Abstract: In this study, a new imine-based tripodal ligand and its difluoroboron complex were designed and synthesized. This trinuclear-boron complex was prepared for the first time and fully characterized by common spectroscopic techniques such as $$^{1}$$1H-NMR,… read more here.
Keywords: boron complex; large stokes; based tripodal; stokes shifts ... See more keywords
Chiral-Boron-Complex-Catalyzed Asymmetric [3 + 2] Cycloaddition of 2'-Hydroxychalcones with N,N'-Cyclic Azomethine Imines.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02597
Abstract: We report the (R)-3,3'-I2-BINOL-boron-complex-catalyzed asymmetric 1,3-dipolar cycloaddition of 2'-hydroxychalcones with N,N'-cyclic azomethine imines, providing the corresponding N,N'-bicyclic pyrazolidine derivatives with three contiguous tertiary stereocenters in high yields with excellent diastereo- and enantioselectivities (up to >99:1… read more here.
Keywords: catalyzed asymmetric; cycloaddition hydroxychalcones; complex catalyzed; boron complex ... See more keywords