Synthesis and Applications of Unquaternized C-Bound Boron Enolates.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b00614
Abstract: A general and facile method to prepare unquaternized C-bound boron enolates by a ligand-controlled O-to-C isomerization is reported. Using this protocol, C-bound pinacolboron enolates have been isolated in pure form for the first time, and… read more here.
Keywords: bound boron; unquaternized bound; applications unquaternized; boron enolates ... See more keywords
Formation of Boron Enolates by Nucleophilic Substitution
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DOI: 10.1055/s-0040-1707181
Abstract: Enolates have proven to be one of the key building blocks available to the synthetic chemist. Here we summarize a novel strategy for their preparation, involving the addition of α-borylated nucleophiles to esters to yield… read more here.
Keywords: nucleophilic substitution; enolates nucleophilic; formation boron; boron enolates ... See more keywords