Photoinduced boron atom insertion of benzocyclobutene forming an unprecedented fused boron heterocyclic radical.
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DOI: 10.1039/d2cc06566e
Abstract: Two novel boron heterocyclic radicals, an addition bicyclo[4.2.1]octa-1,3,5-trien-1-yl-borane radical (A) and an insertion 7-1H-borolo[1,2-a]borinine radical (B), were synthesized, and characterized in the reaction of atomic boron with benzocyclobutene. Species B involving a fused boron heterocyclic… read more here.
Keywords: fused boron; boron; insertion; photoinduced boron ... See more keywords