Versatility of Boron-Mediated Coupling Reaction of Oxetanes and Epoxides with CO2: Selective Synthesis of Cyclic Carbonates or Linear Polycarbonates
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DOI: 10.1021/acssuschemeng.0c04768
Abstract: Achieving simultaneously high selectivity and high rate in the coupling reaction of CO2 with poorly reacting oxetanes remains a major challenge. Here, the selective and nearly quantitative conversi... read more here.
Keywords: boron mediated; versatility boron; coupling reaction; mediated coupling ... See more keywords
General Strategy for the Synthesis of Rare Sugars via Ru(II)-Catalyzed and Boron-Mediated Selective Epimerization of 1,2-trans-Diols to 1,2-cis-Diols.
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DOI: 10.1021/jacs.1c13399
Abstract: Human glycans are primarily composed of nine common sugar building blocks. On the other hand, several hundred monosaccharides have been discovered in bacteria and most of them are not readily available. The ability to access… read more here.
Keywords: catalyzed boron; strategy; boron mediated; general strategy ... See more keywords