Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation
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DOI: 10.1021/acscatal.8b00933
Abstract: The mechanism of boron-to-nickel transmetalation, the key step of the nickel-catalyzed Suzuki-Miyaura (S-M) coupling, was examined both experimentally and theoretically. Dinuclear μ-hydroxo-bridged complexes formed by reaction of trans-[ArNi(PR3)2X] with hydroxide are not directly involved in… read more here.
Keywords: transmetalation; catalyzed suzuki; suzuki miyaura; boron nickel ... See more keywords