Boron-Promoted Umpolung Reaction of Sulfonyl Chlorides for the Stereospecific Synthesis of Thioglycosides via Reductive Deoxygenation Coupling Reactions.
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DOI: 10.1021/acs.orglett.2c00353
Abstract: S-Glycosides have broad biological activities and serve as stable mimics of natural O-glycoside counterparts and thus are of great therapeutic potential. Herein we disclose an efficient method for the stereospecific synthesis of 1-thioglycosides via a… read more here.
Keywords: boron promoted; reductive deoxygenation; thioglycosides via; deoxygenation coupling ... See more keywords