The chiral boronate-catalyzed asymmetric transfer hydrogenation of various aromatic ketones to high-value alcohols: Preparation and spectroscopic studies
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.03.017
Abstract: Abstract This work deals with the synthesis, spectroscopic studies and catalytic evaluation of the novel chiral salen (L1H2) and (L2H2) ligands and their chiral boronate [L1(B1-4)] and [L2(B1-4)] complexes. Initially, the reaction of 5-azidomethyl salicylaldehyde… read more here.
Keywords: chiral boronate; transfer hydrogenation; asymmetric transfer; boronate ... See more keywords
Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01671a
Abstract: A method for the conjunctive functionalization of vinyl boronate complexes with electrophiles is described. The overall process represents a three-component coupling between a vinyl boronic ester, carbon nucleophile and an electrophile, thus affording complex multifunctionalized… read more here.
Keywords: boronate complexes; complexes electrophiles; functionalization vinyl; vinyl ... See more keywords