Halohydroxylation of alkenyl MIDA boronates: switchable stereoselectivity induced by B(MIDA) substituent.
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DOI: 10.1039/d0cc00722f
Abstract: The synthesis of α-boryl halohydrins via difunctionalization of alkenyl MIDA boronates has been reported. Intriguing stereoselectivity was found with different halogen sources, which arises from the special stabilizing effect of the B(MIDA) moiety. The transformation… read more here.
Keywords: mida; halohydroxylation alkenyl; alkenyl mida; stereoselectivity ... See more keywords