Theoretical investigations on P-stabilized boryl cation radicals: from the Aufbau principle to SOMO-HOMO conversion.
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DOI: 10.1039/d2dt02723b
Abstract: We report the characterization of a series of novel phosphinidene-stabilized (P-stabilized) boryl cation radicals, in which the phosphinidene and boryl are stabilised by iPrNHC (iPrNHC[:C{N(iPr)C(H)}2]), and the P-stabilized boryl (P → B) moieties are linked… read more here.
Keywords: stabilized boryl; boryl cation; cation radicals; series ... See more keywords