Beyond the Nucleophilic Role of Metal–Boryl Complexes in Borylation Reactions
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DOI: 10.1021/acscatal.1c00752
Abstract: Transition metal–boryl complexes play an important role as reactive intermediates in catalytic borylation processes and have enjoyed tremendous exploration. Over the years, it has been well establi... read more here.
Keywords: boryl complexes; borylation; role; metal boryl ... See more keywords
Insertion chemistry of iron(II) boryl complexes.
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DOI: 10.1039/d2dt02879d
Abstract: Iron(II) boryl complexes of the pyrrole-based pincer ligand, CyPNP (CyPNP = anion of 2,5-bis(dicyclohexylphophinomethyl)pyrrole) have been synthesized and their insertion reactivity interrogated. Compounds of the type [Fe(BE)(CyPNP)] (E = pinacholato or catecholato) can be generated… read more here.
Keywords: iron boryl; chemistry; boryl complexes; cypnp ... See more keywords
Robust dicopper(i) μ-boryl complexes supported by a dinucleating naphthyridine-based ligand
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DOI: 10.1039/d2sc00848c
Abstract: Copper boryl species have been widely invoked as reactive intermediates in Cu-catalysed C–H borylation reactions, but their isolation and study have been challenging. Use of the robust dinucleating ligand DPFN (2,7-bis(fluoro-di(2-pyridyl)methyl)-1,8-naphthyridine) allowed for the isolation… read more here.
Keywords: boryl; dicopper boryl; boryl complexes; naphthyridine based ... See more keywords