Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction.
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DOI: 10.1021/acs.orglett.1c01567
Abstract: The synthesis of 1,1-diboryl alkenes from terminal alkenes is reported. 1,1-Regioselective addition is observed for both conjugated and unconjugated alkenes, allowing for a single method to prepare a wide range of 1,1-diboryl alkenes. read more here.
Keywords: diboryl alkenes; synthesis diboryl; boryl heck; using boryl ... See more keywords
Synthesis of Trisubstituted Alkenyl Boronic Esters from Alkenes Using the Boryl-Heck Reaction.
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DOI: 10.1021/acs.orglett.8b02949
Abstract: The direct borylation of disubstituted alkenes is reported. These conditions allow for the conversion of a variety 1,1- and 1,2-disubstituted alkenes to trisubstituted alkenyl boronic esters with outstanding yields and excellent E/ Z selectivities. The… read more here.
Keywords: synthesis trisubstituted; boryl heck; reaction; boronic esters ... See more keywords