Synthesis of α-Boryl Ketones via Hydration or Oxidation of B(MIDA)-Decorated Alkynes.
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DOI: 10.1021/acs.orglett.2c04343
Abstract: α-Boryl ketones are traditionally challenging targets in organic synthesis. Reported herein is a mild and metal-free synthesis of α-boryl ketones via the hydration or oxidation of N-methyliminodiacetyl boronate (B(MIDA))-decorated alkynes. A new hydration system comprised… read more here.
Keywords: hydration; synthesis boryl; synthesis; mida ... See more keywords