Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides.
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DOI: 10.1021/acs.inorgchem.1c02124
Abstract: Reactions of 9-carbene-9-borafluorene monoanion (1) with elemental selenium and selenium-containing reagents are reported. When compound 1 is reacted with grey selenium in THF, various boryl-substituted selenides and diselenides are produced (2-6), including molecules resulting from… read more here.
Keywords: boryl substituted; borafluorene monoanion; reactions carbene; carbene borafluorene ... See more keywords
Ruthenium-catalyzed Intermolecular Coupling of Vinylic 1,2-Bisboronates with Alkynes: Stereoselective Access to Boryl-Substituted Homoallylic Alcohols.
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DOI: 10.1021/jacs.0c01755
Abstract: The ruthenium catalytic addition of alkenes to alkynes has been demonstrated as a powerful synthetic tool to form diene motifs and widely applied in the synthesis of complex molecules. How-ever, except for the intramolecular coupling,… read more here.
Keywords: substituted homoallylic; boryl substituted; ruthenium catalyzed; catalyzed intermolecular ... See more keywords