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   Articles with "borylation aryl" as a keyword



Zinc Complexes Supported by Hydroxyl‐Containing Schiff‐Base Ligands as Efficient Catalysts for the Borylation of Aryl Iodides

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recommendations! Published in 2024 at "Asian Journal of Organic Chemistry"

DOI: 10.1002/ajoc.202400247

Abstract: The application of a series of hydroxyl‐containing Schiff‐base ligands in the synthesis of zinc complexes is reported. The substituents on the benzene rings, the positions of the C=N double bonds, and the ratio of the… read more here.

Keywords: containing schiff; zinc complexes; schiff base; hydroxyl containing ... See more keywords
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Iron-Catalyzed Borylation of Aryl Ethers via Cleavage of C-O Bonds.

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recommendations! Published in 2020 at "Organic letters"

DOI: 10.1021/acs.orglett.0c00679

Abstract: Herein, we report the iron-catalyzed borylation of aryl ethers and aryl amines via cleavage of C-O and C-N bonds. This protocol does not require the use of Grignard reagents and displays a broad substrate scope,… read more here.

Keywords: aryl ethers; catalyzed borylation; borylation; via cleavage ... See more keywords

Palladium-Catalyzed Dual-Tasked ortho-C-H Borylation of Aryl Iodides.

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recommendations! Published in 2024 at "Organic letters"

DOI: 10.1021/acs.orglett.4c04218

Abstract: The Pd-catalyzed ortho-C-H borylation of aryl iodides has been developed through maleimide-relayed C-H activation. In this reaction, the ipso-positions and ortho-C-H bonds of aryl iodides are alkylated and borylated, respectively, providing a new strategy for… read more here.

Keywords: ortho borylation; palladium catalyzed; borylation; borylation aryl ... See more keywords

Iron-Catalyzed Borylation of Aryl Trifluoromethoxides.

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recommendations! Published in 2025 at "Organic letters"

DOI: 10.1021/acs.orglett.5c01712

Abstract: The trifluoromethoxy group, a bioisostere of the methoxy group, has emerged as a key functional group in agrochemicals and pharmaceuticals due to its high stability and lipophilicity. While extensive research exists on C(sp2)-OCF3 bond formation,… read more here.

Keywords: catalyzed borylation; aryl trifluoromethoxides; borylation aryl; iron catalyzed ... See more keywords

Cr-catalyzed borylation of C(aryl)-F bonds using a terpyridine ligand.

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recommendations! Published in 2024 at "Chemical communications"

DOI: 10.1039/d4cc01330a

Abstract: The defluoroborylation of fluoroarenes by chromium-catalyzed cleavage of unactivated C-F bonds is described. The reaction uses HBpin as the boron source, low-cost and commercially available chromium salt as the precatalyst, and terpyridine as a crucial… read more here.

Keywords: aryl bonds; ligand; borylation aryl; catalyzed borylation ... See more keywords