Borylation of azines via a Minisci-type reaction
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DOI: 10.1016/j.chempr.2021.06.013
Abstract: C–H borylation of N-heteroarenes is an efficient yet highly challenging route to borylated aromatics. In a recent issue of Nature, Leonori and co-workers demonstrated a novel strategy toward this end by utilizing a boryl-radical-based Minisci-type… read more here.
Keywords: type reaction; borylation azines; minisci type;
A radical approach for the selective C-H borylation of azines.
Sign Up to like & getrecommendations! Published in 2021 at "Nature"
DOI: 10.1038/s41586-021-03637-6
Abstract: Boron functional groups are often introduced in place of aromatic carbon-hydrogen bonds to expedite small-molecule diversification through coupling of molecular fragments1-3. Current approaches based on transition metal-catalysed C-H activation are effective for the borylation of… read more here.
Keywords: borylation; borylation azines; radical approach; approach ... See more keywords