Reductive Ring Opening of Arylcyclopropanecarboxamides Accompanied by Borylation and Enolate Formation.
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DOI: 10.1021/acs.orglett.2c00084
Abstract: Treatment of arylcyclopropanecarboxamides with a sodium dispersion in the presence of methoxypinacolborane as a reduction-resistant electrophile leads to reductive cleavage of the cyclopropane ring followed by instant trapping with the boron electrophile to yield the… read more here.
Keywords: reductive ring; arylcyclopropanecarboxamides accompanied; opening arylcyclopropanecarboxamides; borylation enolate ... See more keywords