Iron-Catalyzed C(Sp3)-H Borylation, Thiolation, and Sulfinylation Enabled by Photoinduced Ligand-to-Metal Charge Transfer.
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DOI: 10.1021/jacs.3c01082
Abstract: Catalytic C(sp3)-H functionalization has provided enormous opportunities to construct organic molecules, facilitating the derivatization of complex pharmaceutical compounds. Within this framework, direct hydrogen atom transfer (HAT) photocatalysis becomes an appealing approach to this goal. However,… read more here.
Keywords: borylation thiolation; sp3 borylation; transfer; thiolation sulfinylation ... See more keywords