Articles with "bottlebrush" as a keyword



Thermoplastic Elastomeric Bottlebrush Copolymer Glue Electrolyte Featuring Dual‐Ion Transport Channels and Strong Segregation: Experimental and Simulation Insights

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Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202515492

Abstract: Despite extensive research on electrolytes for energy storage devices, thermoplastic systems that exhibit elasticity, adhesiveness, and nanostructures remain largely unexplored. Herein, a multifunctional thermoplastic elastomeric glue electrolyte is reported based on a poly(vinyl alcohol)‐g‐poly(2,2,3,3‐tetrafluoropropyl methacrylate)… read more here.

Keywords: bottlebrush; glue electrolyte; ion transport; electrolyte ... See more keywords
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Bottlebrush Elastomers: A New Platform for Freestanding Electroactuation.

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Published in 2017 at "Advanced materials"

DOI: 10.1002/adma.201604209

Abstract: Freestanding, single-component dielectric actuators are designed based on bottlebrush elastomers that enable giant reversible strokes at relatively low electric fields and altogether avoid preactuation mechanical manipulation. This materials design platform allows for independent tuning of… read more here.

Keywords: bottlebrush; new platform; freestanding electroactuation; platform freestanding ... See more keywords

Side Chain Dynamics of poly(norbornene)-g-Poly(propylene oxide) Bottlebrush Polymers.

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Published in 2022 at "Macromolecular rapid communications"

DOI: 10.1002/marc.202200902

Abstract: The segmental dynamics of the side chains of poly(norbornene)-g-poly(propylene oxide) (PNB-g-PPO) bottlebrush polymer in comparison to PPO is studied by quasi-elastic neutron scattering. Having experimental time and length scale information simultaneously allows to extract spatial… read more here.

Keywords: ppo; time; norbornene poly; relaxation ... See more keywords

Host-Guest Interaction Mediated Interfacial Co-Assembly of Cyclodextrin and Bottlebrush Surfactants for Precisely Tunable Photonic Supraballs.

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Published in 2024 at "Small"

DOI: 10.1002/smll.202312099

Abstract: Investigations of host-guest interactions at water-oil (w/o) interfaces are limited in single emulsion systems producing simple self-assembled objects with limited uses. Here, within hierarchically ordered water-in-oil-in-water (w/o/w) multiple emulsion droplets, interfacial self-assembly of (polynorbornene-graft-polystyrene)-block-(polynorbornene-graft-polyethylene glycol)… read more here.

Keywords: bottlebrush surfactants; host guest; photonic supraballs; guest interaction ... See more keywords

Single-Molecule Mechanical Measurements of the Hyaluronan-Aggrecan Bottlebrush

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Published in 2020 at "Biophysical Journal"

DOI: 10.1016/j.bpj.2019.11.1205

Abstract: Large bottlebrush complexes formed from the polysaccharide hyaluronan (HA) and the proteoglycan aggrecan contribute to cartilage compression resistance and are necessary for healthy joint function. A variety of mechanical forces act on these complexes in… read more here.

Keywords: single molecule; measurements hyaluronan; hyaluronan aggrecan; molecule mechanical ... See more keywords

Single-Molecule Stretching Shows Glycosylation Sets Tension in the Hyaluronan-Aggrecan Bottlebrush.

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Published in 2020 at "Biophysical journal"

DOI: 10.1016/j.bpj.2020.08.016

Abstract: Large bottlebrush complexes formed from the polysaccharide hyaluronan (HA) and the proteoglycan aggrecan contribute to cartilage compression resistance and are necessary for healthy joint function. A variety of mechanical forces act on these complexes in… read more here.

Keywords: single molecule; bottlebrush; molecule stretching; glycosylation ... See more keywords

The Concentration Dependence of the Size and Symmetry of a Bottlebrush Polymer in a Good Solvent.

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Published in 2020 at "Macromolecules"

DOI: 10.1021/acs.macromol.0c01181

Abstract: Bottlebrush polymers consist of a linear backbone with densely grafted side chains which impact the rigidity of the molecule. The persistence length of the bottlebrush backbone in solution is influenced by both the intrinsic structure… read more here.

Keywords: bottlebrush; solvent; size; concentration ... See more keywords

Marine Antifouling Coatings Based on Durable Bottlebrush Polymers.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c06647

Abstract: We report a next-generation, biocide-free, and durable marine antifouling coating technology. To achieve this, we combined two different polymers previously developed by us. First, we synthesized well-defined 2-hydroxypropyl acrylamide (HPA) based bottlebrush polymers with concentrated… read more here.

Keywords: coatings based; bottlebrush polymers; based durable; marine antifouling ... See more keywords

Synthesis and Micellization of Bottlebrush Poloxamers.

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Published in 2022 at "ACS macro letters"

DOI: 10.1021/acsmacrolett.2c00053

Abstract: Bottlebrush polymers are characterized by an expansive parameter space, including graft length and spacing along the backbone, and these features impact various structural and physical properties such as molecular diffusion and bulk viscosity. In this… read more here.

Keywords: micellization bottlebrush; molecular weight; bottlebrush poloxamers; graft ... See more keywords

Enhancing Adhesion On-Demand in Bottlebrush Pressure Sensitive Adhesives.

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Published in 2025 at "ACS macro letters"

DOI: 10.1021/acsmacrolett.5c00246

Abstract: There is significant interest in pressure sensitive adhesives that can alter their tackiness on demand. It is particularly desirable to switch adhesion without using additives and chemical agents. In this article, we explore the potential… read more here.

Keywords: pressure sensitive; sensitive adhesives; adhesion; network ... See more keywords

ROMP of Macromonomers Prepared by ROMP: Expanding Access to Complex, Functional Bottlebrush Polymers.

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Published in 2025 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c17151

Abstract: Graft-through ring-opening metathesis polymerization (ROMP) of norbornene-terminated macromonomers (MMs) prepared using various polymerization methods has been extensively used for the synthesis of bottlebrush (co)polymers, yet the potential of ROMP for the synthesis of MMs that… read more here.

Keywords: romp macromonomers; prepared romp; macromonomers prepared; bottlebrush polymers ... See more keywords