Simultaneous Synthesis and Self-Assembly of Bottlebrush Block Copolymers at Room Temperature via Photoinitiated RAFT Dispersion Polymerization.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202100921
Abstract: Bottlebrush polymers exhibiting unique properties have attracted considerable attention for applications in many research areas. Herein, we report the first simultaneous synthesis and self-assembly of bottlebrush block copolymers at room temperature via photoinitiated polymerization-induced self-assembly… read more here.
Keywords: self assembly; block copolymers; block; bottlebrush block ... See more keywords
Thermal annealing induced formation of polymeric nanopillars of asymmetric bottlebrush block copolymers
Sign Up to like & getrecommendations! Published in 2019 at "Polymer"
DOI: 10.1016/j.polymer.2019.121983
Abstract: Abstract Polyhedral polymeric particles are desirable for various applications, but the fabrication is limited due to thermodynamic favorability of sphere formation. Herein, we employed a new strategy to prepare anisotropic nanopillars by thermally annealing bottlebrush… read more here.
Keywords: block copolymers; thermal annealing; bottlebrush block; formation ... See more keywords
Molecular Dynamics Simulation and PRISM Theory Study of Assembly in Solutions of Amphiphilic Bottlebrush Block Copolymers
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.8b01535
Abstract: We use a coarse-grained model with both Polymer Reference Interaction Site Model (PRISM) theory and molecular dynamics (MD) simulations to study self-assembly of amphiphilic bottlebrush block copolymers (BCPs) in solution as a function of increasing… read more here.
Keywords: molecular dynamics; amphiphilic bottlebrush; prism theory; prism ... See more keywords
Self-assembly of POSS-Polystyrene Bottlebrush Block Copolymers on an Angle-Robust Selective Absorber for Enhancing the Purity of Reflective Structural Color.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c11194
Abstract: A facile approach for improving color purity is explored by the introduction of an angle-robust selective absorber (ARSA) into bottlebrush block copolymer (BBCP)-based one-dimensional (1D) photonic crystals (PCs). The BBCPs of poly[(3-(12-(cis-5-norbornene-exo-2,3-dicarboximido)dodecanoylamino)propyl POSS)-block-(norbornene-graft-styrene)], Px (x… read more here.
Keywords: robust selective; color; selective absorber; angle robust ... See more keywords
Complete Photonic Band Gaps with Nonfrustrated ABC Bottlebrush Block Polymers
Sign Up to like & getrecommendations! Published in 2020 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.0c00380
Abstract: Bottlebrush block polymers are a promising platform for self-assembled photonic materials, yet most work has been limited to one-dimensional photonic crystals based on the lamellar phase. Here we d... read more here.
Keywords: bottlebrush block; complete photonic; photonic band; block polymers ... See more keywords
Structural Analysis of Bottlebrush Block Copolymer Micelles Using Small-Angle X-ray Scattering
Sign Up to like & getrecommendations! Published in 2020 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.0c00442
Abstract: We present structural analysis of spherical diblock copolymer micelles where core blocks have bottlebrush architecture. The dependence of the core radius (Rcore) and the corona thickness (Lcorona) ... read more here.
Keywords: structural analysis; copolymer micelles; bottlebrush block; analysis bottlebrush ... See more keywords
Ordered Nanoporous Carbons with Broadly Tunable Pore Size using Bottlebrush Block Copolymer Templates.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09572
Abstract: We report the preparation of ordered porous carbon materials with tailored pore sizes selected between 16 and 108 nanometers using bottlebrush block copolymers (BBCPs) as templates. The nanoporous carbons are prepared via the cooperative assembly… read more here.
Keywords: block; tunable pore; using bottlebrush; size ... See more keywords