Facilely Control Grafting Density and Side Chain Composition of Bottlebrush Polymer.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300047
Abstract: Control over polymer architecture and composition is essential for disclosing structure-property relationships and developing high performance materials. Herein, a new method was successfully developed to synthesize bottlebrush polymer (BP) with controllable graft density and side… read more here.
Keywords: side chain; bottlebrush polymer; composition; side ... See more keywords
Surface forces between bottlebrush polymer layers
Sign Up to like & getrecommendations! Published in 2020 at "Current Opinion in Colloid and Interface Science"
DOI: 10.1016/j.cocis.2019.11.011
Abstract: Abstract In this review, I summarize recent experimental investigations of surface and friction forces between bottlebrush structure macromolecules including biolubricants and biomimetic ones by direct force measurements. I also discuss recent experimental investigations of synergy… read more here.
Keywords: forces bottlebrush; bottlebrush polymer; polymer layers; surface forces ... See more keywords
Supramolecular self-assembly of an ABA-Triblock bottlebrush polymer: Atomic-force microscopy visualization of discrete oligomers
Sign Up to like & getrecommendations! Published in 2017 at "Polymer"
DOI: 10.1016/j.polymer.2017.05.044
Abstract: Abstract A novel ABA-triblock bottlebrush polymer ( PS - PD - PS ), whose terminal PS block and central PD block were densely grafted with polystyrene and poly[2-(dimethylamino)ethyl methacrylate], respectively, on polynorbornene backbones was synthesized… read more here.
Keywords: microscopy; force microscopy; triblock bottlebrush; atomic force ... See more keywords
The Concentration Dependence of the Size and Symmetry of a Bottlebrush Polymer in a Good Solvent.
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.0c01181
Abstract: Bottlebrush polymers consist of a linear backbone with densely grafted side chains which impact the rigidity of the molecule. The persistence length of the bottlebrush backbone in solution is influenced by both the intrinsic structure… read more here.
Keywords: bottlebrush; solvent; size; concentration ... See more keywords
Bottlebrush polymer gels: architectural control over swelling and osmotic bulk modulus.
Sign Up to like & getrecommendations! Published in 2022 at "Soft matter"
DOI: 10.1039/d1sm01575c
Abstract: Swelling behaviour and bulk moduli of polymer gels comprising of crosslinked bottlebrush subchains enable fine tuning by varying polymerization degrees of the main and side chains of the bottlebrush strands as well as their grafting… read more here.
Keywords: modulus; bottlebrush polymer; gels architectural; polymer gels ... See more keywords
Self-healing bottlebrush polymer networks enabled via a side-chain interlocking design.
Sign Up to like & getrecommendations! Published in 2023 at "Materials horizons"
DOI: 10.1039/d3mh00274h
Abstract: Exploring novel healing mechanisms is a constant impetus for the development of self-healing materials. Herein, we find that side-chain interlocking of bottlebrush polymers can form a dynamic network and thereby serve as a driving force… read more here.
Keywords: chain interlocking; side chain; bottlebrush polymer; self healing ... See more keywords