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Charge-transfer complexes based on C2v-symmetric benzo[ghi]perylene: comparison of their dynamic and electronic properties with those of D6h-symmetric coronene

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Published in 2018 at "Materials Chemistry Frontiers"

DOI: 10.1039/c8qm00112j

Abstract: Single crystals of three neutral charge-transfer complexes and a cation radical salt based on a C2v-symmetric polycyclic aromatic hydrocarbon, benzo[ghi]perylene (bper), were obtained. The 1 : 1 complex with 7,7,8,8-tetracyanoquinodimethane (TCNQ) involves DA-type alternating π-columns, whereas the… read more here.

Keywords: transfer complexes; charge transfer; coronene; bper ... See more keywords