Facile Addition of B-H and B-B Bonds to an Iron(IV) Nitride Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02931
Abstract: The nitride ligand in the iron(IV) complex PhB(iPr2Im)3Fe≡N reacts with boron hydrides to afford PhB(iPr2Im)3FeN(B)H (B = 9-BBN (1), Bpin (2)) and with (Bpin)2 to afford PhB(iPr2Im)3FeN(Bpin)2 (3). The iron(II) borylamido products have all been… read more here.
Keywords: phb ipr2im; 3fen bpin; bpin; iron nitride ... See more keywords
Steric Shielding Effects Induced by Intramolecular C-H⋯O Hydrogen Bonding: Remote Borylation Directed by Bpin Groups.
Sign Up to like & getrecommendations! Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.1c05701
Abstract: Regioselectivities in catalytic C-H borylations (CHBs) have been rationalized using simplistic steric models and correlations with nuclear magnetic resonance (NMR) chemical shifts. However, regioselectivity can be significant for important substrate classes where none would be… read more here.
Keywords: hydrogen bonding; shielding effects; intramolecular hydrogen; borylation ... See more keywords