The cocatalyst roles of three anionic Cd(II) porphyrinic metal-organic frameworks in the photocatalytic CO2 reduction to CO process carried out in Ru(bpy)3Cl2/CH3CN/H2O/Triethylamine or triethanolamine system
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DOI: 10.1016/j.jssc.2020.121690
Abstract: Abstract Three 3D, anionic Cd(II) porphyrinic metal-organic frameworks (PMOFs), 1(3.5:1)-2d-120 ([Cd3·2(H2TCPP)2][(CH3)2NH2]1.6), its Li+-exchanged product (e.g. Li+-1-120, formula: [Cd3·2(H2TCPP)2]Li1.6) and 1(10:1)-4d-120 ([Cd3·7H2TCPP)2][(CH3)2NH2]0.6) were synthesized, all of which have the same PXRD pattern. Their VB and CB… read more here.
Keywords: bpy 3cl2; ch3cn; co2 reduction; system ... See more keywords