Thermally Stable Heteroleptic trans‐Bis(chelate) Ruthenium(II) Complex Bearing 2,2'‐Bipyridine and Acetylacetonato: Synthesis, Isomerization, and Crystal Structure
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DOI: 10.1002/ejic.202400243
Abstract: Thermally stable trans‐bis(chelate)‐type Ru(II) complexes are challenging to prepare owing to steric hindrance between the two chelate ligands. Herein, we investigated the isomerization of a heteroleptic cis‐bis(chelate) complex to obtain its trans form. cis‐[Ru(acac)(bpy)(dmso‐S)2](OTf)·0.5H2O (1·(OTf)·0.5H2O;… read more here.
Keywords: bis chelate; otf 5h2o; thermally stable; bpy dmso ... See more keywords