Immobilization of a Molybdenum Complex on Bipyridine-Based Periodic Mesoporous Organosilica and Its Catalytic Activity for Epoxidation of Olefins
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DOI: 10.1021/acscatal.8b00809
Abstract: The dichlorodioxomolybdenum(VI) complex (MoO2Cl2) is an efficient and low-cost homogeneous catalyst for a variety of organic reactions, but its activity usually decreases after immobilization on a solid support. This report describes the synthesis of heterogeneous… read more here.
Keywords: bpy pmo; epoxidation; periodic mesoporous; spectroscopy ... See more keywords
Heterogeneous water oxidation photocatalysis based on periodic mesoporous organosilica immobilizing a tris(2,2′-bipyridine)ruthenium sensitizer
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DOI: 10.1039/d0ra00895h
Abstract: A periodic mesoporous organosilica (PMO) containing 2,2′-bipyridine groups (BPy-PMO) has been shown to possess a unique pore wall structure in which the 2,2′-bipyridine groups are densely and regularly packed. The surface 2,2′-bipyridine groups can function… read more here.
Keywords: bipyridine; water oxidation; bpy pmo; periodic mesoporous ... See more keywords