Synthesis of highly branched polyethylene using para-benzhydryl substituted iminopyridyl Ni(II) and Pd(II) complexes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.11.024
Abstract: Abstract A series of para-benzhydryl substituted iminopyridyl-based Ni(II) and Pd(II) complexes with systematically varied ligand steric, [2,6-R2-4-CHPh2C6H2N = CH(NC6H5)]MX2 (MX2 = NiBr2 or PdCl2; R = -CHPh2 (Ni1,Pd1); R = iPr (Ni2,Pd2); R = Et (Ni3,Pd3); R = Me (Ni4,Pd4)], were synthesized and applied to ethylene oligo-/polymerization… read more here.
Keywords: benzhydryl substituted; para benzhydryl; branched polyethylene; highly branched ... See more keywords
Attaining highly branched polyethylene elastomers by employing modified α-diiminonickel(II) catalysts: Probing the effects of enhancing fluorine atom on the ligand framework towards mechanical properties of polyethylene
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2019.122089
Abstract: Abstract A novel panel of 1-(2,6-dibenzhydryl-3,4-difluorophenylimino)-2-aryliminoacenaphthylenes was synthesized and reacted with (DME)NiBr2 to give rise to mono and di-nuclear complexes with the general formula of LNiBr2 and L2Ni2Br4, respectively. All the ligands were characterized by… read more here.
Keywords: mechanical properties; highly branched; spectroscopy; attaining highly ... See more keywords