Quantum Tunneling in Peroxide O-O Bond Breaking Reaction.
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DOI: 10.1021/jacs.3c02750
Abstract: The importance of quantum-mechanical tunneling becomes increasingly recognized in chemical reactions involving hydrogen as well as heavier atoms. Here we report concerted heavy-atom tunneling in an oxygen-oxygen bond breaking reaction from cyclic beryllium peroxide to… read more here.
Keywords: quantum tunneling; bond breaking; quantum; reaction ... See more keywords