Synthesis of Highly Congested Tertiary Alcohols via the [3,3] Radical Deconstruction of Breslow Intermediates.
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DOI: 10.1021/acs.orglett.2c01627
Abstract: Pericyclic processes such as [3,3]-sigmatropic rearrangements leading to the rapid generation of molecular complexity constitute highly valuable tools in organic synthesis. Herein, we report the formation of particularly hindered tertiary alcohols via rearrangement of Breslow… read more here.
Keywords: synthesis highly; breslow intermediates; highly congested; alcohols via ... See more keywords