The influence of metal centres on the exchange interaction in heterometallic complexes with oxalate-bridged cations.
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DOI: 10.1039/c7dt02522j
Abstract: The reaction of bis(phenanthroline)metal(ii) cations (M = Mn2+, Co2+, Ni2+, Cu2+ and Zn2+) with bis(oxalato)chromium(iii) anions in a water/ethanol solution gives rise to a series of compounds with oxalate-bridged cations, [{M(phen)2}2(μ-C2O4)][Cr(phen)(C2O4)2]2·4H2O [Mn2Cr2 (1), Co2Cr2 (2),… read more here.
Keywords: oxalate bridged; metal; mn2 co2; metal centres ... See more keywords