A rare example of a double metamagnetic transition leading to 2D and 3D long-range order in the two-dimensional pyrazine- and azido-bridged cobalt(II) compound [Co(pyz)(N3)2].
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DOI: 10.1039/d2dt00294a
Abstract: The synthesis, characterization, crystal structure and detailed magnetic properties of a pyrazine (pyz) and azido (N3) bridged cobalt(II) compound of formula [Co(N3)2(pyz)] (1) are reported. Compound 1 shows a layered structure formed by Co(II) chains… read more here.
Keywords: compound; azido bridged; long range; bridged cobalt ... See more keywords
Reversible binding of dinitrogen on a thiolate-bridged cobalt-ruthenium complex supported by a flexible bidentate phosphine ligand.
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DOI: 10.1039/d2dt01534j
Abstract: A well-defined thiolate-bridged cobalt-ruthenium complex is demonstrated to reversibly bind N2 by modulation of the auxiliary phosphine ligand, which is evidenced by time-dependent 1H NMR spectroscopy at different temperatures. Notably, this heterobimetallic system represents the… read more here.
Keywords: cobalt ruthenium; bridged cobalt; phosphine ligand; ruthenium complex ... See more keywords