Articles with "bridged coordination" as a keyword



Synthesis, crystal structure and dielectric properties of a new acetate bridged coordination polymer: {[La(μ-CH3COO)(PDC)(H2O)2].2H2O}n

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Published in 2019 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2019.05.119

Abstract: Abstract An acetate bridged coordination polymer of lanthanum, formulated as {[La(μ-CH3COO)(PDC)(H2O)2].2H2O}n (H2PDC = pyridine-3,4-dicarboxylic acid) has been successfully grown by single gel diffusion technique at room temperature using hydrosilica gel and further characterized by elemental analysis, powder… read more here.

Keywords: h2o 2h2o; bridged coordination; acetate bridged; ch3coo pdc ... See more keywords

Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]2+

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Published in 2022 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.2c01629

Abstract: A series of new CN-bridged coordination networks of different dimensionality and topology was obtained through the modification of reaction conditions between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [W(CN)8]4–. The factors determining the reaction pathway are temperature… read more here.

Keywords: network; coordination; bridged coordination; li2 cyclam ... See more keywords

Cyanide bridged coordination polymer nanoflakes thermally derived Ni3C and fcc-Ni nanoparticles for electrocatalysts

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Published in 2017 at "New Journal of Chemistry"

DOI: 10.1039/c7nj03311g

Abstract: We report a controlled crystal growth process that enables the design of monocrystalline cyanide bridged coordination polymer (NiCNNi CP) nanoflakes using trisodium citrate dihydrate (TSCD) to control the nucleation rate. TSCD reacted with Ni2+ in… read more here.

Keywords: fcc nanoparticles; cyanide bridged; coordination polymer; bridged coordination ... See more keywords
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Large breathing effect induced by water sorption in a remarkably stable nonporous cyanide-bridged coordination polymer†

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Published in 2021 at "Chemical Science"

DOI: 10.1039/d1sc02060a

Abstract: While metal–organic frameworks (MOFs) are at the forefront of cutting-edge porous materials, extraordinary sorption properties can also be observed in Prussian Blue Analogs (PBAs) and related materials comprising extremely short bridging ligands. Herein, we present… read more here.

Keywords: cyanide bridged; water; nonporous cyanide; bridged coordination ... See more keywords

Bridged Ov-Ru-O-Co coordination induced by Co2+δ substitution in Co/RuO2 Catalysts for Enhanced Alkaline Hydrogen and Oxygen Evolution

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Published in 2025 at "Journal of Materials Chemistry A"

DOI: 10.1039/d5ta02960k

Abstract: Tailoring a highly active and stable alkaline electrocatalyst endowed with an ultra-low electron transfer energy barrier towards hydrogen/oxygen evolution reactions (HER/OER) has remained elusive to date. Herein, a defect-rich nanoporous... read more here.

Keywords: bridged coordination; oxygen evolution; hydrogen oxygen;