Synthesis, crystal structure and dielectric properties of a new acetate bridged coordination polymer: {[La(μ-CH3COO)(PDC)(H2O)2].2H2O}n
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.05.119
Abstract: Abstract An acetate bridged coordination polymer of lanthanum, formulated as {[La(μ-CH3COO)(PDC)(H2O)2].2H2O}n (H2PDC = pyridine-3,4-dicarboxylic acid) has been successfully grown by single gel diffusion technique at room temperature using hydrosilica gel and further characterized by elemental analysis, powder… read more here.
Keywords: h2o 2h2o; bridged coordination; acetate bridged; ch3coo pdc ... See more keywords
Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]2+
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DOI: 10.1021/acs.inorgchem.2c01629
Abstract: A series of new CN-bridged coordination networks of different dimensionality and topology was obtained through the modification of reaction conditions between [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [W(CN)8]4–. The factors determining the reaction pathway are temperature… read more here.
Keywords: network; coordination; bridged coordination; li2 cyclam ... See more keywords
Cyanide bridged coordination polymer nanoflakes thermally derived Ni3C and fcc-Ni nanoparticles for electrocatalysts
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DOI: 10.1039/c7nj03311g
Abstract: We report a controlled crystal growth process that enables the design of monocrystalline cyanide bridged coordination polymer (NiCNNi CP) nanoflakes using trisodium citrate dihydrate (TSCD) to control the nucleation rate. TSCD reacted with Ni2+ in… read more here.
Keywords: fcc nanoparticles; cyanide bridged; coordination polymer; bridged coordination ... See more keywords
Large breathing effect induced by water sorption in a remarkably stable nonporous cyanide-bridged coordination polymer†
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Science"
DOI: 10.1039/d1sc02060a
Abstract: While metal–organic frameworks (MOFs) are at the forefront of cutting-edge porous materials, extraordinary sorption properties can also be observed in Prussian Blue Analogs (PBAs) and related materials comprising extremely short bridging ligands. Herein, we present… read more here.
Keywords: cyanide bridged; water; nonporous cyanide; bridged coordination ... See more keywords