Theoretical study of magnetic interaction in pyrazole-bridged dinuclear Cu(II) complex
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.03.017
Abstract: Abstract A difference in a magnetic behavior of two different types of pyrazole-bridged dinuclear Cu(II) complexes are explained by a concept of the orbital complementarity and the density functional theory (DFT) calculations. The DFT calculations… read more here.
Keywords: theoretical study; study magnetic; magnetic interaction; pyrazole bridged ... See more keywords
Sulphido bridged dinuclear quadruple bond cleavage product from the reaction between Re2(µ-O2CCH3)4Cl2 and dithiocarbamate: An experimental and theoretical study
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115422
Abstract: Abstract Sodium salts of dimethyldithiocarbamate, diethyldithiocarbamate and pyrrolidinedithiocarbamate react with the quadruply bonded dirhenium(III,III) complex [Re2(μ-O2CCH3)4Cl2] (1) in ethanol to afford the sulphido bridged dinuclear quadruple-bond cleavage products of the type [Re2(μ-S)(LR)4(OH2)2] (2(LR)) where LR… read more here.
Keywords: o2cch3 4cl2; sulphido bridged; bridged dinuclear; re2 o2cch3 ... See more keywords
Versatile coordination architectures of products generated by the in situ reaction of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear copper(ii) complex with tetracyanoethylene
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce00036d
Abstract: Reaction of doubly bpypz− bridged Cu(ii) dinuclear complex and TCNE gave three versatile coordination assemblies with TCNE solvolysis derivatives, depending on reaction solvents. read more here.
Keywords: coordination architectures; reaction doubly; bridged dinuclear; reaction ... See more keywords
Chloranilate bridged dinuclear copper(ii) complexes: syn–anti geometry tuned by the steric factor and supramolecular interactions
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DOI: 10.1039/c9ce00705a
Abstract: The anti-conformation of chloranilate bridged di-copper complexes of NNO donor Schiff-base ligands is more stable than the syn-conformation, but the latter is stabilised by CH⋯π and hydrogen bonding interactions between solvent of crystallisation and chloranilate… read more here.
Keywords: copper complexes; geometry; dinuclear copper; chloranilate bridged ... See more keywords
Structure Controlling Factors of Oxido-Bridged Dinuclear Iron(III) Complexes
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DOI: 10.3390/molecules26040897
Abstract: Oxido bridges commonly form between iron(III) ions, but their bond angles and symmetry vary with the circumstances. A large number of oxido-bridged dinuclear iron(III) complexes have been structurally characterized. Some of them belong to the… read more here.
Keywords: dinuclear iron; bridged dinuclear; iron; oxido bridged ... See more keywords
New Nucleic Base-Tethered Trithiolato-Bridged Dinuclear Ruthenium(II)-Arene Compounds: Synthesis and Antiparasitic Activity
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27238173
Abstract: Aiming toward compounds with improved anti-Toxoplasma activity by exploiting the parasite auxotrophies, a library of nucleobase-tethered trithiolato-bridged dinuclear ruthenium(II)-arene conjugates was synthesized and evaluated. Structural features such as the type of nucleobase and linking unit… read more here.
Keywords: ruthenium arene; tethered trithiolato; trithiolato bridged; activity ... See more keywords