Articles with "bridged dirhodium" as a keyword



Photo by theian20 from unsplash

Highly β( Z)-Selective Hydrosilylation of Terminal Alkynes Catalyzed by Thiolate-Bridged Dirhodium Complexes.

Sign Up to like & get
recommendations!
Published in 2018 at "Organic letters"

DOI: 10.1021/acs.orglett.8b02267

Abstract: A series of novel monothiolate-bridged dirhodium complexes, [Cp*Rh(μ-SR)(μ-Cl)2RhCp*][BF4] {Cp* = η5-C5Me5, R = tertiary butyl ( tBu), 1a; R = ferrocenyl (Fc), 1b; R = adamantyl (Ad), 1c} were designed and successfully synthesized, which can… read more here.

Keywords: dirhodium complexes; dirhodium; terminal alkynes; hydrosilylation terminal ... See more keywords