Cyanido‐Bridged FeII–MI Dimetallic Hofmann‐Like Spin‐Crossover Coordination Polymers Based on 2,6‐Naphthyridine
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DOI: 10.1002/ejic.201700920
Abstract: Two new 3D spin crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1) and {Fe(2,6-naphthy)[Au(CN)2]2}·(0,5)PhNO2 (2) (2,6-naphthy = 2,6-naphthyridine) have been synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2[Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered… read more here.
Keywords: feii dimetallic; bridged feii; spin crossover; coordination polymers ... See more keywords