Computational study of ground-state properties of μ2 -bridged group 14 porphyrinic sandwich complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of computational chemistry"
DOI: 10.1002/jcc.26870
Abstract: The structural properties of μ2 -bridged porphyrinic double-decker complexes are investigated and the influence of various ligands, metals, substituents, and bridging atoms on the dominant structural motif is elucidated. A variety of quantum chemical methods… read more here.
Keywords: bridged group; ground state; computational study; properties bridged ... See more keywords
Fast Photochromism of the Imidazole Dimers Bridged by Group 14 Atoms.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02072
Abstract: We developed fast photochromic imidazole dimers bridged by group 14 atoms. These compounds reversibly break the C-N bond to generate the colored open-ring biradical form. The colored form thermally reproduces the initial colorless form in… read more here.
Keywords: imidazole dimers; bridged group; group atoms; fast photochromism ... See more keywords