Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers featuring single-chain magnet behavior.
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DOI: 10.1039/d0dt00181c
Abstract: Two azido-bridged homospin Fe(ii)/Co(ii) coordination polymers [Fe2(Bzp)2(N3)4]n (1) and [Co4(Bzp)4(N3)8·(MeOH)2]n (2) (bzp = 2-benzoylpyridine) are prepared, which consist of one-dimensional neutral chains with pure EO-azido (μ2-1,1-N3) bridges. Magnetically, both 1 and 2 exhibit considerable intrachain… read more here.
Keywords: chain; bridged homospin; homospin coordination; azido bridged ... See more keywords