Synthesis and reactivity of hydride-bridged ruthenium dithiolene complexes
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DOI: 10.1016/j.poly.2017.10.023
Abstract: Abstract Syntheses of two homonuclear hydride complexes, viz. hydride-bridged ruthenium dinuclear complex [Ru(η6-C6Me6)(S2C6H4)RuClH(PPh3)2] (3) and dihydride ruthenium dinuclear complex [Ru(η6-C6Me6)(S2C6H4) RuH2(PPh3)2] (4), have been described. Complex 4 was obtained as a mixture of cis- and… read more here.
Keywords: ruthenium; pph3; dinuclear complex; bridged ruthenium ... See more keywords
A thiolate-bridged ruthenium-molybdenum complex featuring terminal nitrido and bridging amido ligands derived from the N-H and N-N bond cleavage of hydrazine.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01378a
Abstract: Biomimetic di- or multimetallic complexes featuring NxHy species in a sulfur-rich coordination sphere have attracted considerable attention in modelling the possible scenarios of biological nitrogen fixation by nitrogenases. Although the active site of nitrogenases is… read more here.
Keywords: bridged ruthenium; complex featuring; molybdenum complex; hydrazine ... See more keywords