A cyanide-bridged wheel featuring a seven-coordinate Mo(iii) center.
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DOI: 10.1039/c8cc09373c
Abstract: A new cyclic molecule incorporating [MoIII(CN)7]4- has been characterized by single crystal X-ray methods, SQUID magnetometry and theoretical calculations. The wheel molecule [MoIII(CN)7]6[Ni(L)]12(H2O)6 exhibits ferromagnetic Mo-Ni coupling which did not exist for the previously reported… read more here.
Keywords: bridged wheel; wheel featuring; cyanide bridged; seven coordinate ... See more keywords