A μ-AsO4-Bridging Hexadecanuclear Ni-Substituted Polyoxotungstate.
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DOI: 10.1021/acs.inorgchem.1c00056
Abstract: A novel tetrahedral μ-AsO4-bridging hexadecanuclear Ni-substituted silicotungstate (ST) Na21H10[(AsO4){Ni8(OH)6(H2O)2(CO3)2(A-α-SiW9O34)2}2]·60H2O (1) was made by the reactions of trivacant [A-α-SiW9O34]10- ({SiW9}) units with Ni2+ cations and Na3AsO4·12H2O and characterized by IR spectrometry, elemental analysis, thermogravimetric analysis (TGA),… read more here.
Keywords: aso4 bridging; aso4 ni8; bridging hexadecanuclear; chemistry ... See more keywords