Covalent-bond-enhanced photocatalytic hydrogen evolution of C3N4/CoPx with L-cysteine molecule as bridging ligands
Sign Up to like & getrecommendations! Published in 2021 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2021.151025
Abstract: Abstract Serious interface carrier recombination leads to moderated photocatalytic performance of carbon nitride (C3N4), and the realization of their strongly covalent bonding with co-catalysts can efficiently inhibit this. In this article, C3N4 nanosheets are first… read more here.
Keywords: copx; cysteine; bridging ligands; c3n4 copx ... See more keywords
Multinuclear Pd and Pt complexes with bridging Si- and Ge-ligands. Stable and flexible coordination bonds and structures and reactions of the molecules
Sign Up to like & getrecommendations! Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213195
Abstract: Abstract Late transition metal complexes with metal-silicon or metal-germanium σ bond show the chemical properties that could not be found for the complexes with metal-carbon σ bond. In this article, we review reports on the… read more here.
Keywords: coordination; bridging ligands; bond; metal complexes ... See more keywords
Elucidation of Excited-State Properties of Bimetallic Ir(III)–Pt(II) Complexes with Conjugated Bridging Ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b06665
Abstract: We investigated excited-state properties of 4′,7′-phenanthrolino-5′,6′:2,3-pyrazine (ppz)-bridged bimetallic complexes, (L)2Ir-ppz-PtCl2 (Ir-ppz-Pt) (L = 2-(4′,6′-difluorophenyl)pyridinato-N,C2 (dfppy)), and [(L)2Ir]2(ppz) (Ir-ppz-Ir). These properties were compared to those of reported dpp bridging complexes, 2,3-bis(2-pyridyl)pyrazine (dpp)-bridged bimetallic complexes, Ir-dpp-Pt, and… read more here.
Keywords: state; elucidation excited; excited state; bridging ligands ... See more keywords
From Chelating to Bridging Ligands: N-Sulfonyliminoimidazolium Ylides as Precursors to Anionic N-Heterocyclic Carbene Ligands
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DOI: 10.1021/acs.organomet.8b00764
Abstract: The synthesis and investigation of a new family of anionic N-heterocyclic carbene (NHC) ligands, based on N-sulfonyliminoimidazolium ylides, is reported. Their corresponding silver complexes have been synthesized and present distinctive geometries compared to the previously… read more here.
Keywords: chelating bridging; bridging ligands; anionic heterocyclic; sulfonyliminoimidazolium ylides ... See more keywords