Pd-Catalyzed 1,4-Carboamination of Bicyclic Bromoarenes with Diazo Compounds and Amines.
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DOI: 10.1021/acs.orglett.2c01233
Abstract: A palladium-catalyzed 1,4-carboamination of bromoarenes with diazo compounds and amines was developed. This reaction proceeds through a palladium-carbene that then generates a π-benzylpalladium intermediate, forming ipso C-C and para C-N bonds on bromoarenes in a… read more here.
Keywords: carboamination bicyclic; bromoarenes diazo; diazo compounds; catalyzed carboamination ... See more keywords