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Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.12.019
Abstract: Abstract In the following study, we investigated thermally and photolytically induced transformations of acylcyclotetrasilanes (Me3Si)2Si4Me8(Me3Si)COR (compounds 9a-c; R = alkyl, aryl). Mild thermolysis of 9a-c below 130 °C cleanly and selectively afforded the corresponding endocyclic silenes 10b-d irrespective…
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Keywords:
thermal brook;
silenes thermal;
endocyclic silenes;
brook rearrangement ... See more keywords
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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02392
Abstract: A novel mechanism of organobase-mediated Brook rearrangement and C-C coupling in the copper-catalyzed reductive coupling of benzaldehyde and benzophenone is proposed. The results demonstrate that this reaction proceeds mainly through five sequential elementary steps: transmetalation,…
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Keywords:
coupling copper;
reductive coupling;
coupling benzaldehyde;
brook rearrangement ... See more keywords
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Published in 2019 at "RSC Advances"
DOI: 10.1039/c9ra05482k
Abstract: Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess.
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Keywords:
chirality transfer;
rearrangement silyl;
asymmetric retro;
brook rearrangement ... See more keywords