Synthetic Strategy for AB2-Type Arsines via Bidentate Dithiolate Leaving Groups.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01974
Abstract: Despite their potential for several transition-metal-catalyzed reactions, arsenic ligands are poorly diversified. In this work, we developed an efficient synthetic methodology for AB2-type ligands, which is a typical motif in phosphorus systems, for example, in… read more here.
Keywords: buchwald ligands; type arsines; ab2 type; reaction ... See more keywords
Exploring the Utility of Buchwald Ligands for C–H Oxidative Direct Arylation Polymerizations
Sign Up to like & getrecommendations! Published in 2019 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.9b00395
Abstract: Oxidative C–H/C–H cross-coupling polymerizations provide an opportunity to synthesize conjugated polymers with an increased ease of monomer preparation, reduced environmental impact, and increased sustainability. Considering these attributes, it is necessary to expand the diversity of… read more here.
Keywords: coupling polymerizations; cross coupling; buchwald ligands; direct arylation ... See more keywords
Steric and electronic effects of arsa-Buchwald ligands on Suzuki-Miyaura coupling reaction.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt04139a
Abstract: The Suzuki-Miyaura coupling (SMC) reaction is one of the most commonly used cross-coupling reactions. Bulky biaryldialkyl monophosphine ligands, i.e., Buchwald ligands, are beneficial for the SMC reaction. We recently developed a synthetic procedure for arsa-Buchwald… read more here.
Keywords: reaction; suzuki miyaura; steric electronic; buchwald ligands ... See more keywords