Glycolaldehyde as a Bio‐Based C1 Building Block for Selective N‐Formylation of Secondary Amines
Sign Up to like & getrecommendations! Published in 2022 at "Chemsuschem"
DOI: 10.1002/cssc.202201264
Abstract: Abstract Biomass derived glycolaldehyde was employed as C1 building block for the N‐formylation of secondary amines using air as oxidant. The reaction is atom economic, highly selective and proceeds under catalyst free conditions. This strategy… read more here.
Keywords: building block; formylation secondary; secondary amines;
Methanol Activation: Strategies for Utilization of Methanol as C1 Building Block in Sustainable Organic Synthesis.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202401974
Abstract: The development of efficient and sustainable chemical processes which use greener reagents and solvents, currently play an important role in current research. Methanol, a cheap and readily available resource from chemical industry, could be activated… read more here.
Keywords: building block; activation strategies; methanol activation; activation ... See more keywords
HFO‐1234yf as a CF 3 ‐Building Block: Synthesis and Chemistry of CF 3 ‐Ynones
Sign Up to like & getrecommendations! Published in 2020 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202001071
Abstract: Reaction of low cost, readily available 4th generation refrigerant gas 2,3,3,3‐tetrafluoropropene (HFO‐1234yf) with lithium diisopropylamide (LDA) leads to formation of lithium 3,3,3‐trifluoropropynide, addition of which to a range of aldehydes formed CF3‐alkynyl alcohol derivatives on… read more here.
Keywords: building block; block synthesis; chemistry; 1234yf building ... See more keywords
Eugenol: A Promising Building Block for Synthesis of Radically Polymerizable Monomers
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201900179
Abstract: Eugenol, a natural phenol currently mainly obtained from clove oil, is an interesting aromatic building block for the synthesis of novel biobased monomers. It can also be obtained from lignin depolymerization, becoming a promising building… read more here.
Keywords: building block; promising building; building; block synthesis ... See more keywords
Sequence building block for magnetic resonance spectroscopy on Siemens VE‐series scanners
Sign Up to like & getrecommendations! Published in 2024 at "NMR in Biomedicine"
DOI: 10.1002/nbm.5165
Abstract: We present a sequence building block (SBB) that embeds magnetic resonance spectroscopy (MRS) into another sequence on the Siemens VE platform without any custom hardware. This enables dynamic studies such as functional MRS (fMRS), dynamic… read more here.
Keywords: spectroscopy; sequence building; magnetic resonance; sequence ... See more keywords
Organic β-cyclodextrin Nanoparticle: An Efficient Building Block Between Functionalized Poly(pyrrole) Electrodes and Enzymes.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202105880
Abstract: Glyconanoparticles (GNPs) made by self-assembly of carbohydrate-based polystyrene-block-β-cyclodextrin copolymer are used as a building block for the design of nanostructured biomaterials of electrode. The firm immobilization of GNPs is carried out on electrochemically generated polymer,… read more here.
Keywords: block; poly pyrrole; building block; organic cyclodextrin ... See more keywords
Side-Gated Iontronic Memtransistor: A Fast and Energy-Efficient Neuromorphic Building Block.
Sign Up to like & getrecommendations! Published in 2025 at "Small"
DOI: 10.1002/smll.202408175
Abstract: Iontronic memtransistors have emerged as technologically superior to conventional memristors for neuromorphic applications due to their low operating voltage, additional gate control, and enhanced energy efficiency. In this study, a side-gated iontronic organic memtransistor (SG-IOMT)… read more here.
Keywords: energy; memtransistor; energy efficient; side gated ... See more keywords
Photochromic difurylethene bisaldehyde as potential building block for [AA] and [AB]2 macrocyclization
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-019-02538-x
Abstract: Catalyst- and template-free condensation of photochromic difurylethene bisaldehyde with o-phenylenediamine led to selective formation of macrocyclic Schiff base [AB]2 product. Application of the same difurylethene bisaldehyde in the McMurry reaction resulted in cyclic dimer formation… read more here.
Keywords: photochromic difurylethene; difurylethene; bisaldehyde potential; building block ... See more keywords
A new building block with intramolecular D-A character for conjugated polymers: ladder structure based on B←N unit
Sign Up to like & getrecommendations! Published in 2019 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9518-7
Abstract: The general strategy to construct D-A type conjugated polymers is alternating copolymerization of electron-donating (D) monomer and electron-accepting (A) monomer. In this article, we report a new strategy to develop D-A type conjugated polymers, i.e.… read more here.
Keywords: block; unit; building block; conjugated polymers ... See more keywords
A cyanide-bridged one-dimensional CrIIICoII metamagnet based on the trans-dicyanidechromate(III) building block
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.03.034
Abstract: Abstract A cyanide-bridged CrIIICoII bimetallic complex [Cr(bpb)(CN)2Co(LN5)·2H2O·ClO4]n (bpb2− = 1,2-bis(pyridine-2-carboxamido)benzenate, LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene) (1) has been synthesized by the reaction of [CoII(LN5)(H2O)2](ClO4)2 with the trans-dicyanidechromate(III) building block K[CrIII(bpb)(CN)2]. X-ray single crystal diffraction analysis shows that complex 1 exhibits a… read more here.
Keywords: dicyanidechromate iii; cyanide bridged; building block; trans dicyanidechromate ... See more keywords
Molecular and macromolecular crowding-induced stabilization of proteins: Effect of dextran and its building block alone and their mixtures on stability and structure of lysozyme.
Sign Up to like & getrecommendations! Published in 2019 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2019.10.135
Abstract: Dextran 70 and its building block (glucose) has been used as macromolecular crowder and osmolyte, respectively. The difference in size and structure of both made us inquisitive to measure stability of lysozyme in the presence… read more here.
Keywords: dextran building; stabilization; building block; dextran ... See more keywords