Glycolaldehyde as a Bio‐Based C1 Building Block for Selective N‐Formylation of Secondary Amines
Sign Up to like & getrecommendations! Published in 2022 at "Chemsuschem"
DOI: 10.1002/cssc.202201264
Abstract: Abstract Biomass derived glycolaldehyde was employed as C1 building block for the N‐formylation of secondary amines using air as oxidant. The reaction is atom economic, highly selective and proceeds under catalyst free conditions. This strategy… read more here.
Keywords: building block; formylation secondary; secondary amines;
HFO‐1234yf as a CF 3 ‐Building Block: Synthesis and Chemistry of CF 3 ‐Ynones
Sign Up to like & getrecommendations! Published in 2020 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202001071
Abstract: Reaction of low cost, readily available 4th generation refrigerant gas 2,3,3,3‐tetrafluoropropene (HFO‐1234yf) with lithium diisopropylamide (LDA) leads to formation of lithium 3,3,3‐trifluoropropynide, addition of which to a range of aldehydes formed CF3‐alkynyl alcohol derivatives on… read more here.
Keywords: building block; block synthesis; chemistry; 1234yf building ... See more keywords
Eugenol: A Promising Building Block for Synthesis of Radically Polymerizable Monomers
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201900179
Abstract: Eugenol, a natural phenol currently mainly obtained from clove oil, is an interesting aromatic building block for the synthesis of novel biobased monomers. It can also be obtained from lignin depolymerization, becoming a promising building… read more here.
Keywords: building block; promising building; building; block synthesis ... See more keywords
Organic β-cyclodextrin Nanoparticle: An Efficient Building Block Between Functionalized Poly(pyrrole) Electrodes and Enzymes.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202105880
Abstract: Glyconanoparticles (GNPs) made by self-assembly of carbohydrate-based polystyrene-block-β-cyclodextrin copolymer are used as a building block for the design of nanostructured biomaterials of electrode. The firm immobilization of GNPs is carried out on electrochemically generated polymer,… read more here.
Keywords: block; poly pyrrole; building block; organic cyclodextrin ... See more keywords
Photochromic difurylethene bisaldehyde as potential building block for [AA] and [AB]2 macrocyclization
Sign Up to like & getrecommendations! Published in 2019 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-019-02538-x
Abstract: Catalyst- and template-free condensation of photochromic difurylethene bisaldehyde with o-phenylenediamine led to selective formation of macrocyclic Schiff base [AB]2 product. Application of the same difurylethene bisaldehyde in the McMurry reaction resulted in cyclic dimer formation… read more here.
Keywords: photochromic difurylethene; difurylethene; bisaldehyde potential; building block ... See more keywords
A new building block with intramolecular D-A character for conjugated polymers: ladder structure based on B←N unit
Sign Up to like & getrecommendations! Published in 2019 at "Science China Chemistry"
DOI: 10.1007/s11426-019-9518-7
Abstract: The general strategy to construct D-A type conjugated polymers is alternating copolymerization of electron-donating (D) monomer and electron-accepting (A) monomer. In this article, we report a new strategy to develop D-A type conjugated polymers, i.e.… read more here.
Keywords: block; unit; building block; conjugated polymers ... See more keywords
A cyanide-bridged one-dimensional CrIIICoII metamagnet based on the trans-dicyanidechromate(III) building block
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.03.034
Abstract: Abstract A cyanide-bridged CrIIICoII bimetallic complex [Cr(bpb)(CN)2Co(LN5)·2H2O·ClO4]n (bpb2− = 1,2-bis(pyridine-2-carboxamido)benzenate, LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene) (1) has been synthesized by the reaction of [CoII(LN5)(H2O)2](ClO4)2 with the trans-dicyanidechromate(III) building block K[CrIII(bpb)(CN)2]. X-ray single crystal diffraction analysis shows that complex 1 exhibits a… read more here.
Keywords: dicyanidechromate iii; cyanide bridged; building block; trans dicyanidechromate ... See more keywords
Molecular and macromolecular crowding-induced stabilization of proteins: Effect of dextran and its building block alone and their mixtures on stability and structure of lysozyme.
Sign Up to like & getrecommendations! Published in 2019 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2019.10.135
Abstract: Dextran 70 and its building block (glucose) has been used as macromolecular crowder and osmolyte, respectively. The difference in size and structure of both made us inquisitive to measure stability of lysozyme in the presence… read more here.
Keywords: dextran building; stabilization; building block; dextran ... See more keywords
Building block candidates for the design of proton exchange membranes: Maleimide and its homologues
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DOI: 10.1016/j.ijhydene.2016.10.099
Abstract: Abstract Density functional theory (DFT) calculations are applied to the study of proton transport in maleimide and its homologues, succinimide and phthalimide. The calculations reproduce correctly their structural characteristics and reveal the hydrogen bonding and… read more here.
Keywords: proton exchange; block candidates; building block; maleimide homologues ... See more keywords
First principles investigation of the electronic properties of graphitic carbon nitride with different building block and sheet staggered arrangement
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Alloys and Compounds"
DOI: 10.1016/j.jallcom.2017.11.061
Abstract: Abstract The electronic properties of g-C3N4 with different building block and sheet staggered arrangement are studied by using first-principles calculations. The calculated lattice constants and band gaps of bulk g-C3N4 with different space group P-6m2,… read more here.
Keywords: staggered arrangement; electronic properties; sheet staggered; building block ... See more keywords
Smart lighting as basic building block of smart city: An energy performance comparative case study
Sign Up to like & getrecommendations! Published in 2019 at "Measurement"
DOI: 10.1016/j.measurement.2018.12.095
Abstract: Abstract The aim of this work is to simulate and compare the energy savings potentially applicable to the consumption data of the Smart Street pilot system located at the ENEA Casaccia R.C. (Rome). The astronomical… read more here.
Keywords: basic building; building block; lighting basic; smart lighting ... See more keywords