Bithiazole Dicarboxylate Ester: An Easily Accessible Electron-Deficient Building Unit for π-Conjugated Polymers Enabling Electron Transport
Sign Up to like & getrecommendations! Published in 2021 at "Macromolecules"
DOI: 10.1021/acs.macromol.1c00080
Abstract: Thiazole has been less focused, compared to thiophene, as the building unit for π-conjugated polymers that are used in organic electronic devices despite its electron deficiency and ability to copl... read more here.
Keywords: bithiazole dicarboxylate; unit conjugated; electron; building unit ... See more keywords
Nickel(II) metal–organic frameworks with N,N′-di(4-pyridyl)-naphthalenediimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce00956a
Abstract: When Ni(NO3)2·6H2O and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, analogous reactions with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) and DPNDI affords two-dimensional, pillared metal–organic frameworks. 2 and… read more here.
Keywords: building unit; secondary building; metal organic; geometry ... See more keywords
Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01635b
Abstract: The NiII complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and 1H NMR spectra, provided an anionic species as the building unit of… read more here.
Keywords: building unit; unit ion; pairing assembly; ion pairing ... See more keywords
Fully developed building unit cavity source for long multiple shallow cavity configurations
Sign Up to like & getrecommendations! Published in 2018 at "Physics of Fluids"
DOI: 10.1063/1.5041751
Abstract: Fluid resonant oscillations have been reported for corrugated pipes installed in offshore gas and oil fields. Corrugated pipes can be modelled as a series of consecutive shallow cavities. The current study investigates the development of… read more here.
Keywords: fully developed; cavity source; building unit; source ... See more keywords
A polyoxometalate-based metal-organic polyhedron constructed from a {V5O9Cl} building unit with rhombicuboctahedral geometry.
Sign Up to like & getrecommendations! Published in 2018 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229618010689
Abstract: The design and construction of metal-organic polyhedra has received much attention by chemists due to the intriguing diversity of architectures and topologies that can be achieved. There are several crucial factors which should be considered… read more here.
Keywords: v5o9cl building; geometry; building unit; metal organic ... See more keywords
Naphthobispyrazine as an Electron-deficient Building Unit for π-Conjugated Polymers: Efficient Synthesis and Polymer Properties
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry Letters"
DOI: 10.1246/cl.170445
Abstract: Naphthobispyrazine (NPz), a family of naphthalene-based electron-deficient fused heteroaromatic rings, and its derivatives including a polymer are efficiently synthesized via the ring-opening reaction of corresponding naphthobisthiadiazole derivatives. The electrochemical and optical measurements of the NPz-based… read more here.
Keywords: building unit; deficient; deficient building; polymer ... See more keywords
Cyclic [Cu-biRadical]2 Secondary Building Unit in 2p-3d and 2p-3d-4f Complexes: Crystal Structure and Magnetic Properties
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28062514
Abstract: Employing the new nitronyl nitroxide biradical ligand biNIT-3Py-5-Ph (2-(5-phenyl-3-pyridyl)-bis(4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)), a 16-spin Cu-radical complex, [Cu8(biNIT-3Py-5-Ph)4(hfac)16] 1, and three 2p-3d-4f chain complexes, {[Ln(hfac)3][Cu(hfac)2]2(biNIT-3Py-5-Ph)2}n (LnⅢ= Gd 2, Tb 3, Dy 4; hfac = hexafluoroacetylacetonate), have been prepared and… read more here.
Keywords: building unit; secondary building; binit 3py;