Activation of C−H Bond of Propane by Strong Basic Sites Generated by Bulk Proton Conduction on V‐Modified Hydroxyapatites for the Formation of Propene.
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DOI: 10.1002/cctc.201902181
Abstract: Insights into the catalytic transformation of propane to propene on V‐apatite catalysts are provided based on structure‐reactivity relationships. Substitution of phosphates by vanadates in the hydroxyapatite structure leads to the formation of Ca10(PO4)6‐x(VO4)x(OH)2‐yOy V‐oxy‐hydroxy‐apatite solid… read more here.
Keywords: proton; propane; bulk proton; activation ... See more keywords
Surface modification enhances the bulk proton conductivity of Prussian blue.
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DOI: 10.1039/d3cc00629h
Abstract: Surface-modified Prussian blue shows 102 times higher bulk proton conductivity (0.018 S cm-1) than that of unmodified Prussian blue. This enhancement is attributed to the monolayer adsorption of Na4[Fe(CN)6] on the nanoparticle surface, which reduces… read more here.
Keywords: proton conductivity; prussian blue; bulk proton; surface ... See more keywords