Diiron butane-1,2-dithiolate complexes with tris(2-thienyl)phosphine, tris(4-trifluoromethylphenyl)phosphine, or 4-(dimethylamino)phenyldiphenylphosphine: synthesis, characterization, X-ray crystal structures, and electrochemistry
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DOI: 10.1080/15421406.2020.1726669
Abstract: Abstract In this paper, three diiron butane-1,2-dithiolate complexes have been prepared and characterized. Treatment of the starting complex [Fe2(CO)6{µ-SCH2CH(CH2CH3)S}] (1) with a monophosphine ligand tris(2-thienyl)phosphine, tris(4-trifluoromethylphenyl)phosphine, or 4-(dimethylamino)phenyldiphenylphosphine and Me3NO·2H2O as the decarbonylating agent gave… read more here.
Keywords: diiron butane; phosphine; butane dithiolate; tris ... See more keywords