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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00888
Abstract: A Mannich reaction of deprotonated, highly enantioenriched α,α-disubstituted N-tert-butanesulfinyl ketimines with isatin-derived ketimines was developed to prepare 3-amino-3-substituted oxindoles bearing an acyclic quaternary stereogenic carbon substituted with two sterically similar groups. The excellent stereocontrol of…
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Keywords:
butanesulfinyl ketimines;
ketimines isatin;
disubstituted tert;
tert butanesulfinyl ... See more keywords
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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03801
Abstract: A single-flask cascade of Michael addition and Wittig olefination was developed to allow the stereoselective α-allylic alkylation of α-branched N-tert-butanesulfinyl ketimines for the construction of acyclic quaternary stereocenters bearing two sterically and electronically similar substituents.…
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Keywords:
tert butanesulfinyl;
construction acyclic;
butanesulfinyl ketimines;
acyclic quaternary ... See more keywords